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2011 Fiscal Year Final Research Report

Efficiency improvement of high-temperature process by hybrid of chemical heat storage function

Research Project

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Project/Area Number 20360428
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Energy engineering
Research InstitutionTokyo Institute of Technology

Principal Investigator

KATO Yukitaka  東京工業大学, 原子炉工学研究所, 准教授 (20233827)

Co-Investigator(Kenkyū-buntansha) RYU Junichi  東京工業大学, 原子炉工学研究所, 助教 (70376937)
Project Period (FY) 2008 – 2011
Keywords化学蓄熱 / ハイブリッド / 高温プロセス / 負荷平準化 / 排熱回収
Research Abstract

Feasibility of hybrid thermal energy system which combines magnesium oxide/water chemical heat storage system and high-temperature process was discussed experimentally as an energy saving system. New heat storage composite material mixed with expanded graphite and magnesium hydroxide was demonstrated as high-performance material compared with conventional pure magnesium hydroxide. Pelletized material using the composite was developed also. The pellet was charged into a packed bed reactor of chemical heat storage system and measured its thermal performance. The chemical heat storage system using the composite was expected to contribute on load leveling and energy saving of a high-temperature process.

  • Research Products

    (35 results)

All 2012 2011 2010 2009 2008 Other

All Journal Article (5 results) (of which Peer Reviewed: 4 results) Presentation (23 results) Book (3 results) Remarks (1 results) Patent(Industrial Property Rights) (3 results)

  • [Journal Article] Durability of Lithium Chloride-Modied Magnesium Hydroxide on Cyclic Operation for Chemical Heat Pump2012

    • Author(s)
      Hirokazu Ishitobi, Keirei Uriuma, Junichi Ryu, Yukitaka Kato
    • Journal Title

      J. Chem. Eng. Japan

      Volume: Vol.45, No.1 Pages: 58-63

    • Peer Reviewed
  • [Journal Article] Reactivity Enhancement of Chemical Materials Used in Packed Bed Reactor of Chemical Heat Pump2011

    • Author(s)
      Seon Tae KIM, Junichi RYU, Yukitaka KATO
    • Journal Title

      Progress in Nuclear Energy

      Volume: 53 Pages: 1027-1033

  • [Journal Article] Development of Chemical Heat Pumps for Utilization of Low-temperature Waste Heats(Review Paper)2009

    • Author(s)
      Y. Kato
    • Journal Title

      J. Jpn. Inst. Energy

      Volume: 88(11) Pages: 986-993

    • Peer Reviewed
  • [Journal Article] Study on medium-temperature chemical heat storage using mixed hydroxides2009

    • Author(s)
      Y. Kato, R. Takahashi, T. Sekiguchi, J. Ryu
    • Journal Title

      J. Intn' 1 J of Refrigeration

      Volume: 32(4) Pages: 661-666

    • DOI

      doi:10.1016/j.ijrefrig.2009.01.032

    • Peer Reviewed
  • [Journal Article] Dehydration Behavior of Metal-salt-added Magnesium Hydroxide as Chemical Heat Storage Media2008

    • Author(s)
      J. Ryu, N. Hirao, R. Takahashi, Y. Kato
    • Journal Title

      Chemistry Letters

      Volume: 37(11) Pages: 1140-1141

    • Peer Reviewed
  • [Presentation] Reactivity Enhance of Packed Bed Chemical Material Using Expanded Graphite for Chemical Heat Pump2012

    • Author(s)
      Seon Tae KIM, Junichi RYU, Yukitaka KATO
    • Organizer
      Proceedings of the 12th International Conference on Energy Storage(Innostock 2012) Lleida, Spain
    • Place of Presentation
      INNO-ST-04(Poster)
    • Year and Date
      2012-05-16
  • [Presentation] Effect of Lithium Bromide on Chemical Heat Storage Materials with Expanded Graphite2012

    • Author(s)
      Myagmarjav O., Kim S. T., Ryu Jun-ichi, Kato Yukitaka
    • Organizer
      化学工学会第77年会
    • Place of Presentation
      工学院大学
    • Year and Date
      2012-03-16
  • [Presentation] The optimization of expanded graphite mixture as a chemical heat storage material2012

    • Author(s)
      Kim Seontae, Uruma Keirei, Ryu Junichi, Kato Yukitaka
    • Organizer
      化学工学会第77年会
    • Place of Presentation
      工学院大学
    • Year and Date
      2012-03-16
  • [Presentation] 希土類複合水酸化物の化学蓄熱材料への適用2012

    • Author(s)
      石飛宏和、水野峻史、宇留間慶麗、劉醇一、加藤之貴
    • Organizer
      化学工学会第77年会
    • Place of Presentation
      工学院大学
    • Year and Date
      2012-03-16
  • [Presentation] Optimization of magnesium hydroxide to expanded graphite mixing ratio for chemical heat pump2012

    • Author(s)
      Zamengo Massimiliano, Kim Seon Tae, Ryu Junichi, Kato Yukitaka
    • Organizer
      化学工学会第77年会
    • Place of Presentation
      工学院大学
    • Year and Date
      2012-03-16
  • [Presentation] Performances of a MgO-expanded graphite packed bed reactor of chemical heat pump2011

    • Author(s)
      Zamengo Massimiliano, Seon-Tae Kim, Ryu Junichi, Kato Yukitaka
    • Organizer
      SCEJ 76^<nd> Annual Meeting
    • Place of Presentation
      Tokyo Univ. A & T, Tokyo
    • Year and Date
      20110322-24
  • [Presentation] Expanded graphite mixture for packed bed reactor of chemical heat pump2011

    • Author(s)
      Kim Seon Tae, Uruma Keirei, Ryu Junichi, Kato Yukitaka
    • Organizer
      SCEJ 76^<nd> Annual Meeting
    • Place of Presentation
      Tokyo Univ. A & T, Tokyo
    • Year and Date
      20110322-24
  • [Presentation] Packed bed reactor chemical heat pump : performances of expanded graphite/Mg(OH)_2 pellets2011

    • Author(s)
      Zamengo Massimiliano、Ryu Junichi、Kato Yukitaka
    • Organizer
      化学工学会第43回秋季大会
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      2011-09-14
  • [Presentation] マグネシウム-コバルト系複合水酸化物を用いた化学蓄熱に関する研究2011

    • Author(s)
      水野峻史、石飛宏和、宇留間慶麗、劉醇一、加藤之貴
    • Organizer
      化学工学会第43回秋季大会
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      2011-09-14
  • [Presentation] [Keynote Lecture] DEVELOPMENT OF CHEMICAL HEAT PUMP FOR RECOVERY OF WASTE HEAT AT MIDDLE TEMPERATURES OF 200-400℃2011

    • Author(s)
      Y. Kato
    • Organizer
      VIII Minsk International Seminar "Heat Pipes, Heat Pumps, Refrigerators, Power Sources"
    • Place of Presentation
      Minsk, Belarus
    • Year and Date
      2011-09-13
  • [Presentation] Expanded graphite mixture reactant for packed bed reactor of chemical heat pump2011

    • Author(s)
      Seon Tae Kim, Junichi Ryu, Yukitaka Kato
    • Organizer
      Proc. of International Sorption Heat Pump Conference(ISHPC11)
    • Place of Presentation
      Padua, Italy
    • Year and Date
      2011-06-08
  • [Presentation] The reactivity of metal salt-modified materials for chemical heat pump in a repetitive reaction2011

    • Author(s)
      H. Ishitobi, K. Uruma, J. Ryu, Y. Kato
    • Organizer
      Proc. of International Sorption Heat Pump Conference(ISHPC11)
    • Place of Presentation
      Padua, Italy
    • Year and Date
      2011-06-08
  • [Presentation] Dehydration and Hydration Behavior of LiCl-Modified Mg(OH)_2 as a Material for Chemical Heat Pumps2010

    • Author(s)
      Hirokazu ISHITOBI, Yoshitomo SATO, Keirei URUMA, Junichi RYU, and Yukitaka KATO
    • Organizer
      Proc. of Int' l Symposium on Innovative Materials for Processes in Energy Systems 2010(IMPRES2010)
    • Place of Presentation
      Furama Riverfront Hotel, Singapore
    • Year and Date
      2010-11-30
  • [Presentation] Dehydration and Hydration Behavior of Magnesium-Aluminum Mixed Hydroxide for Chemical Heat Pump2010

    • Author(s)
      Junichi RYU, Rui TAKAHASHI, Hirokazu ISHITOBI, Yoshitomo SATO, Keirei URUMA, Yukitaka KATO
    • Organizer
      Proc. of Int' l Symposium on Innovative Materials for Processes in Energy Systems 2010(IMPRES2010)
    • Place of Presentation
      Furama Riverfront Hotel, Singapore
    • Year and Date
      2010-11-30
  • [Presentation] マグネシウムを利用したケミカルヒートポンプによる余剰熱の有効利用2010

    • Author(s)
      加藤之貴
    • Organizer
      日本鉄鋼協会第160回秋季講演大会、グリーンエネルギーフォーラム「マグネシウムとエネルギー」
    • Place of Presentation
      北海道大学
    • Year and Date
      2010-09-26
  • [Presentation] REACTIVITY ENHANCEMENT OF CHEMICAL MATERIALS FOR PACKED BED REACTOR OF CHEMICAL HEAT PUMP2010

    • Author(s)
      Kim Seon Tae, J. Ryu, Y. Kato
    • Organizer
      SCEJ 42^<nd> Autumn Meeting
    • Place of Presentation
      Doshisha Univ.
    • Year and Date
      2010-09-06
  • [Presentation] マグネシウム-遷移金属系複合水酸化物の化学蓄熱への適用2010

    • Author(s)
      佐藤義智、石飛宏和、宇留間慶麗、劉醇一、加藤之貴
    • Organizer
      化学工学会第42回秋期大会
    • Place of Presentation
      同志社大学
    • Year and Date
      2010-09-06
  • [Presentation] 塩化リチウム修飾水酸化マグネシウムの繰り返し反応に対する耐久性2010

    • Author(s)
      石飛宏和、佐藤義智、宇留間慶麗、劉醇一、加藤之貴
    • Organizer
      化学工学会第42回秋期大会
    • Place of Presentation
      同志社大学
    • Year and Date
      2010-09-06
  • [Presentation] 金属塩添加水酸化マグネシウムの脱水反応特性2010

    • Author(s)
      石飛宏和,劉醇一,加藤之貴
    • Organizer
      化学工学会第75年会
    • Place of Presentation
      鹿児島大学
    • Year and Date
      2010-03-18
  • [Presentation] 金属塩添加水酸化マグネシウムの水和反応特性と化学蓄熱への適用2009

    • Author(s)
      石飛宏和、平尾直也、劉醇一、加藤之貴
    • Organizer
      化学工学会第41回秋季大会
    • Place of Presentation
      広島大学
    • Year and Date
      2009-09-17
  • [Presentation] THERMAL ENERGY STORAGES IN VEHICLES FOR FUEL EFFICIENCY IMPROVEMENT2009

    • Author(s)
      Y. Kato
    • Organizer
      Proc. of The 11th Intl Conference on Thermal Energy Storage(Effstock 2009)
    • Place of Presentation
      Stockholm, Sweden
    • Year and Date
      2009-06-15
  • [Presentation] 金属塩添加水酸化マグネシウムのケミカルヒートポンプへの適用2009

    • Author(s)
      平尾直也、劉醇一、石飛宏和、加藤之貴
    • Organizer
      化学工学会第74年会
    • Place of Presentation
      横浜国大、横浜
    • Year and Date
      2009-03-20
  • [Presentation] Reactor Study on Middle Temperature Heat Storage using Chemical Composite Materials2008

    • Author(s)
      Y. Kato, R. Takahashi, T. Sekiguchi, J. Ryu
    • Organizer
      Proc. of International Sorption Heat Pump Conference 2008
    • Place of Presentation
      Seoul, KOREA
    • Year and Date
      20080923-26
  • [Book] ゼロから見直すエネルギー節電、総エネからスマートグリッドまで2012

    • Author(s)
      加藤之貴、松形正彦・古山通久編
    • Total Pages
      22-29, 110-114
    • Publisher
      丸善
  • [Book] 実装可能なエネルギー技術で築く未来-骨太のエネルギーロードマップ2-2010

    • Author(s)
      加藤之貴、安永裕幸、柏木孝夫監修
    • Total Pages
      346
    • Publisher
      化学工業社
  • [Book] 水蒸気脱着型蓄熱材による熱輸送技術"、「エネルギーの貯蔵・輸送電気・熱・化学」、エヌ・ティー・エス2008

    • Author(s)
      加藤之貴
    • Total Pages
      273-286
  • [Remarks]

    • URL

      http://www.nr.titech.ac.jp/~yukitaka/

  • [Patent(Industrial Property Rights)] 化学蓄熱材及びケミカルヒートポンプ2011

    • Inventor(s)
      加藤之貴、ザメンゴマッシミリアーノ、キムションテ、劉醇一
    • Industrial Property Rights Holder
      東京工業大学
    • Industrial Property Number
      特許、特願2011-257935
    • Filing Date
      2011-11-25
  • [Patent(Industrial Property Rights)] ケミカルヒートポンプ2011

    • Inventor(s)
      加藤之貴、劉醇一、高橋塁
    • Industrial Property Rights Holder
      東京工業大学
    • Industrial Property Number
      特許、第4765072号
    • Acquisition Date
      2011-06-24
  • [Patent(Industrial Property Rights)] ケミカルヒートポンプ装置およびその運転方法2008

    • Inventor(s)
      加藤之貴、太田秀之、佐藤洋司
    • Industrial Property Rights Holder
      東京工業大学、(株)電業社
    • Industrial Property Number
      特許、第4145051号
    • Acquisition Date
      2008-06-27

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Published: 2013-07-31  

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