2010 Fiscal Year Final Research Report
Synthesis of Hypervalent Organobromanes(III) and Their Synthetic Organic Reactions
| Project/Area Number |
20390005
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Chemical pharmacy
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| Research Institution | The University of Tokushima |
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Principal Investigator |
OCHIAI Masahito The University of Tokushima, 大学院・ヘルスバイオサイエンス研究部, 教授 (50127065)
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| Co-Investigator(Kenkyū-buntansha) |
MIYAMOTO Kazunori 徳島大学, 大学院・ヘルスバイオサイエンス研究部, 助教 (40403696)
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| Project Period (FY) |
2008 – 2010
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| Keywords | イリド / 臭素 / ヨウ素 / カルベン / ナイトレン / 超原子価 / アジリジン |
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| Research Abstract |
We have developed the following new chemistry of hypervalent organobromane (III).
(1) Thermal generation of singlet carbene (carbenoid) from hypervalent bromonium ylides.
(2) The first synthesis of hypervalent organo iminobromane(III).
(3) Development of new reactions using hypervalent iminobromane(III) as an organonitrenoid.
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