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2011 Fiscal Year Final Research Report

Development of an efficient method for chemical recycling plastics and cellulose using supercritical alcohol and organocatalysts

Research Project

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Project/Area Number 21310052
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Environmental technology/Environmental materials
Research InstitutionYamaguchi University

Principal Investigator

KAMIMURA Akio  山口大学, 大学院・医学系研究科, 教授 (30194971)

Co-Investigator(Kenkyū-buntansha) TSUTSUMI Hiromori  山口大学, 大学院・医学系研究科, 教授 (90211383)
OKAMOTO Hiroaki  山口大学, 大学院・理工学研究科, 准教授 (10274185)
Co-Investigator(Renkei-kenkyūsha) TSUTSUMI Hiromori  山口大学, 大学院・医学系研究科, 教授 (90211383)
OKAMOTO Hiroaki  山口大学, 大学院・理工学研究科, 准教授 (10274185)
Project Period (FY) 2009 – 2011
Keywords環境技術 / セルロース / 超臨界流体 / 廃棄物再資源化
Research Abstract

Cellulose underwent solubilization and decomposition by treatment with supercritical Me0H in the presence of alkali metal salt of acetate. Products were divided by using MeOH and CHC1_3. MeOH-soluble components, which was the largest fraction of the products, consisted with at least three compounds, which were neither aromatic compounds such as 5-HMF nor glucose. Thus, this decomposition reaction of cellulose should be a new reaction that will give new types of cellulose-derived products. The optimization of the reaction conditions was also examined.

  • Research Products

    (4 results)

All 2011 2010 2009 Other

All Presentation (3 results) Remarks (1 results)

  • [Presentation] 超臨界アルコールを用いたセルロースの新しい解重合2011

    • Author(s)
      伊藤剛孝, 山田和男, 松谷三樹, 上村明男
    • Organizer
      日本化学会西日本大会
    • Place of Presentation
      徳島,徳島大学常三島キヤンパス
    • Year and Date
      2011-11-12
  • [Presentation] Depolymerization of cellulose in supercritical MeOH2010

    • Author(s)
      Akiko Fujita, Kazuo Yamada, and Akio Kamimura
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies(PACIFICHEM2010)
    • Place of Presentation
      Convention center, Honolulu, Hawaii, USA
    • Year and Date
      2010-12-19
  • [Presentation] Supercritical Lower Alcohols as a Useful Media for Depolymerization of Plastics2009

    • Author(s)
      Akio Kamimura
    • Organizer
      9th International Symposium on Supercritical Fluids(ISSF2009)
    • Place of Presentation
      Palais des Congres d' Arcachon, Arcachon, France
    • Year and Date
      2009-05-20
  • [Remarks]

    • URL

      http://perkin.chem.yamaguchi-u.ac.jp

URL: 

Published: 2013-07-31  

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