2012 Fiscal Year Final Research Report
Synthesis of Optically Active Flower-inducing Fatty Acids, KODA Analogs
| Project/Area Number |
22580114
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (C)
|
| Allocation Type | Single-year Grants |
|---|
| Section | 一般 |
|---|
| Research Field |
Bioproduction chemistry/Bioorganic chemistry
|
|---|
| Research Institution | Ibaraki University |
|---|
Principal Investigator |
|
|---|
| Project Period (FY) |
2010 – 2012
|
| Keywords | KODA / 脂肪酸 / シクロプロパン / 花芽誘導活性 / 植物ホルモン様活性 / 化学合成 / 光学活性類縁体 |
|---|
| Research Abstract |
Stereoselective synthesis of promising flower-inducing fatty acids, KODA analogs, was designed to obtain the desired stereoisomer viacoupling between chiral sulfone and aldehyde segments. Coupling of the both segments and subsequent assembly gave the desired analog. This strategy made it possible to synthesize the remaining stereoisomeric analogs. By using synthetic KODA analogs, the study of mechanistic elucidation of flower-inducing activity by KODA and the development of flower-inducing regulator are expected to progress.
|
