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2013 Fiscal Year Final Research Report

Development and application of rare-earth free red and green phosphors

Research Project

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Project/Area Number 23360133
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionGunma University

Principal Investigator

ADACHI Sadao  群馬大学, 理工学研究院, 教授 (10202631)

Co-Investigator(Kenkyū-buntansha) NAKAMURA Toshihiro  群馬大学, 理工学研究院, 助教 (90451715)
Project Period (FY) 2011-04-01 – 2014-03-31
Keywords蛍光体
Research Abstract

The results obtained in this study were:
(1)Various I2-IV-F6:Mn4+ red phosphors, (2) various II-IV-F6:Mn4+ red phosphors, (3) Na2SiF6:Mn2+ yellow phosphor, (4) CaCO3 phosphors, (5) SnO2 phosphors, and (6) Ga2O3 phosphors were synthesized and systematically evaluated using various experimental techniques. For the development of future nanostructured phosphor materials, the luminescent properties of some compound semiconductors and porous Si materials were also investigated. Moreover, Si nanowire structure was realized using a metal-particle/galvanic-cell system.

  • Research Products

    (48 results)

All 2014 2013 2012 2011

All Journal Article (43 results) (of which Peer Reviewed: 43 results) Presentation (1 results) Book (3 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Simple wet chemical synthesis and photoluminescence characterization of SnO_2 : Eu^<3+> reddish-orange phosphor2014

    • Author(s)
      T. Arai and S. Adachi
    • Journal Title

      J. Lumin

      Volume: 153 Pages: 46-53

    • DOI

      10.1016/j.jlumin.2014.03.011

    • Peer Reviewed
  • [Journal Article] Emission decay rate of a light emitter on thin metal films2014

    • Author(s)
      T. Nakamura, T. Moriyama, N. Nabatova-Gabain and S. Adachi
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: 53 Pages: 045201-1-5

    • DOI

      10.7567/JJAP.53.045201

    • Peer Reviewed
  • [Journal Article] Synthesis and optical properties of BaTiF_6 : Mn^<4+> red phosphor2014

    • Author(s)
      D. Sekiguchi and S. Adachi
    • Journal Title

      ECS J. Solid State Sci. Technol

      Volume: 3 Pages: R60-R64

    • DOI

      10.1149/2.025404jss

    • Peer Reviewed
  • [Journal Article] High energy transfer efficiency in photoluminescence of (Ce^<3+>, Tb^<3+>)-codoped NaCl green phosphor2014

    • Author(s)
      Y. Nagaoka and S. Adachi
    • Journal Title

      ECS J. Solid State Sci. Technol

      Volume: 3 Pages: R43-R49

    • DOI

      10.1149/2.006404jss

    • Peer Reviewed
  • [Journal Article] Synthesis and properties of "black silicon" formed by Pd-catalyst etching in NH_4HF_2/H_2O_2 solution2014

    • Author(s)
      Y. Matsui and S. Adachi
    • Journal Title

      ECS J. Solid State Sci. Technol

      Volume: 3 Pages: 48-54

    • DOI

      10.1149/2.004404jss

    • Peer Reviewed
  • [Journal Article] Plasmonic control of ZnO random lasing characteristics2014

    • Author(s)
      T. Nakamura, S. Sonoda, and S. Adachi
    • Journal Title

      Laser Phys. Lett

      Volume: 11 Pages: 016004-1-5

    • DOI

      10.1088/16122011/11/1/016004

    • Peer Reviewed
  • [Journal Article] Effects of Ce concentration and temperature on photoluminescence intensity in KCl : Ce^<3+> blue phosphor2014

    • Author(s)
      Y. Tosaka and S. Adachi
    • Journal Title

      ECS J. Solid State Sci. Technol

      Volume: 3 Pages: R14-R17

    • DOI

      10.1149/2.008402jss

    • Peer Reviewed
  • [Journal Article] Photoluminescent properties of NaCl : Ce^<3+> phosphor synthesized using antisolvent crystallization2014

    • Author(s)
      Y. Nagaoka and S. Adachi
    • Journal Title

      J. Lumin

      Volume: 145 Pages: 797-802

    • DOI

      10.1016/j.jlumin.2013.08.062

    • Peer Reviewed
  • [Journal Article] Optical spectroscopy of ZnSiF_6・6H_2O : Mn^<4+> red phosphor2013

    • Author(s)
      R. Hoshino and S. Adachi
    • Journal Title

      J. Appl. Phys

      Volume: 114 Pages: 213502-1-6

    • DOI

      10.1063/1.4836896

    • Peer Reviewed
  • [Journal Article] Photoluminescent properties of Eu^<3+> in G_2O_3 : Cr^<3+> films prepared by metal organic deposition2013

    • Author(s)
      Y. Tokida and S. Adachi
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: 52 Pages: 101102-1-5

    • DOI

      10.7567/JJAP.52.101102

    • Peer Reviewed
  • [Journal Article] IR emission band and multiple-peak structure in photoluminescence spectra of SnO_2 : Mn2013

    • Author(s)
      T. Arai and S. Adachi
    • Journal Title

      ECS J. Solid State Sci. Technol

      Volume: 2 Pages: R172-R177

    • DOI

      10.1149/2.029309jss

    • Peer Reviewed
  • [Journal Article] Efficient resonant energy transfer in (Ce^<3+>, Tb^<3+>)-codoped CaCO_3 green phosphor2013

    • Author(s)
      J. Nara and S. Adachi
    • Journal Title

      ECS J. Solid State Sci. Technol

      Volume: 2 Pages: R135-R141

    • DOI

      10.1149/2.016307jss

    • Peer Reviewed
  • [Journal Article] Photoluminescence and Raman scattering spectroscopies of BaSiF_6 : Mn^<4+> red phosphor2013

    • Author(s)
      D. Sekiguchi, J. Nara, and S. Adachi
    • Journal Title

      J. Appl. Phys

      Volume: 113 Pages: 183516-1-6

    • DOI

      10.1063/1.4803880

    • Peer Reviewed
  • [Journal Article] Optical properties of "black silicon" formed by catalytic etching of Au/Si(100) wafers2013

    • Author(s)
      Y. Matsui and S. Adachi
    • Journal Title

      J. Appl. Phys

      Volume: 113 Pages: 173502-1-9

    • DOI

      10.1063/1.4803152

    • Peer Reviewed
  • [Journal Article] Optical absorption, photoluminescence, and Raman scattering studies on Si nanowire arrays formed in Ag_2SO_4-HF-H_2O solution2013

    • Author(s)
      H. Tomioka and S. Adachi
    • Journal Title

      ECS J. Solid State Sci. Technol

      Volume: 2 Pages: 253-258

    • DOI

      10.1149/2.007306jss

    • Peer Reviewed
  • [Journal Article] Photoluminescence properties of (Ce^<3+>, Mn^<2+>)-codoped CaCO_3 red phosphor2013

    • Author(s)
      J. Nara and S. Adachi
    • Journal Title

      J. Appl. Phys

      Volume: 113 Pages: 033519-1-9

    • DOI

      10.1063/1.4779856

    • Peer Reviewed
  • [Journal Article] Optical properties of NaCl : Sn^<2+> phosphor synthesized from aqueous NaCl/SnCl_2/HCl solution2013

    • Author(s)
      M. Kondo and S. Adachi
    • Journal Title

      ECS J. Solid State Sci. Technol

      Volume: 2 Pages: R9-R15

    • DOI

      10.1149/2.029301jss

    • Peer Reviewed
  • [Journal Article] Strongly modified spontaneous emission decay rate of silicon nanocrystals near semicontinuous gold films2012

    • Author(s)
      T. Nakamura, B. P. Tiwari, and S. Adachi
    • Journal Title

      Opt. Express

      Volume: 20 Pages: 26548-26558

    • DOI

      10.1364/OE.20.026548

    • Peer Reviewed
  • [Journal Article] Electron-hole plasma lasing in a ZnO random laser2012

    • Author(s)
      T. Nakamura, K. Firdaus, and S. Adachi
    • Journal Title

      Phys. Rev

      Volume: B 86 Pages: 205103-1-7

    • DOI

      10.1103/PhysRevB.86.205103

    • Peer Reviewed
  • [Journal Article] Photoluminescence spectroscopy and energy-level analysis of metal-organic-deposited Ga_2O_3 : Cr^<3+> films2012

    • Author(s)
      Y. Tokida and S. Adachi
    • Journal Title

      J. Appl. Phys

      Volume: 112 Pages: 063522-1-9

    • DOI

      10.1063/1.4754517

    • Peer Reviewed
  • [Journal Article] Synthesis and photoluminescence properties of SnO_2 nanopowder2012

    • Author(s)
      T. Arai and S. Adachi
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: 51 Pages: 105002-1-5

    • DOI

      10.1143/JJAP.51.105002

    • Peer Reviewed
  • [Journal Article] Properties of magnetic nickel/porous-silicon composite powders2012

    • Author(s)
      T. Nakamura and S. Adachi
    • Journal Title

      AIP Adv

      Volume: 2 Pages: 032167-1-12

    • DOI

      10.1063/1.4754152

    • Peer Reviewed
  • [Journal Article] Optical properties of porous silicon layers formed by el ectroless photovoltaic etching2012

    • Author(s)
      Y. Matsui and S. Adachi
    • Journal Title

      ECS J. Solid State Sci. Technol

      Volume: 1 Pages: R80-R85

    • DOI

      10.1149/2.017202jss

    • Peer Reviewed
  • [Journal Article] Photoluminescence properties of SnO_2H_2O phosphor2012

    • Author(s)
      T. Arai and S. Adachi
    • Journal Title

      ECS J. Solid State Sci. Technol

      Volume: 1 Pages: R15-R21

    • DOI

      10.1149/2.005201jss

    • Peer Reviewed
  • [Journal Article] Photoluminescence decay dynamics of silver/porous-Si nanocomposites formed by metal-assisted etching2012

    • Author(s)
      T. Nakamura and S. Adachi
    • Journal Title

      J. Lumin

      Volume: 132 Pages: 3019-3026

    • DOI

      10.1016/j.jlumin.2012.06.031

    • Peer Reviewed
  • [Journal Article] Mn-activated K_2ZrF_6 and Na_2ZrF_6 phosphors : Sharp red and oscillatory blue-green emissions2012

    • Author(s)
      R. Kasa and S. Adachi
    • Journal Title

      J. Appl. Phys

      Volume: 112 Pages: 013506-1-6

    • DOI

      10.1063/1.4732139

    • Peer Reviewed
  • [Journal Article] Improved lasing characteristics of ZnO/organic-dye random laser2012

    • Author(s)
      K. Firdaus, T. Nakamura, and S. Adachi
    • Journal Title

      Appl. Phys. Lett

      Volume: 100 Pages: 171101-1-4

    • DOI

      10.1063/1.4705471

    • Peer Reviewed
  • [Journal Article] Fabrication and optical characterization of Si nanowires formed by catalytic chemical etching in Ag_2O/HF solution2012

    • Author(s)
      Y. Kato and S. Adachi
    • Journal Title

      Appl. Surf. Sci

      Volume: 258 Pages: 5689-5697

    • DOI

      10.1016/j.apsusc.2012.02.063

    • Peer Reviewed
  • [Journal Article] Phosphorous and boron codoping of silicon nanocrystals by ion implantation : Photoluminescence properties2012

    • Author(s)
      T. Nakamura, S. Adachi, M. Fujii, K. Miura, and S. Yamamoto
    • Journal Title

      Phys. Rev

      Volume: B 85 Pages: 045441-1-7

    • DOI

      10.1103/PhysRevB.85.045441

    • Peer Reviewed
  • [Journal Article] Red and deep red emissions from cubic K_2SiF_6 : Mn^<4+> and hexagonal K_2MnF_6 synthesized in HF/KMnO_4/KHF_2/Si solutions2012

    • Author(s)
      R. Kasa and S. Adachi
    • Journal Title

      J. Electrochem. Soc

      Volume: 159 Pages: J89-J95

    • DOI

      10.1149/2.005204jes

    • Peer Reviewed
  • [Journal Article] Synthesis and properties of hetero-dialkaline hexafluorosilicate red phosphor KNaSiF_6 : Mn^<4+>2012

    • Author(s)
      S. Adachi, H. Abe, R. Kasa, and T. Arai
    • Journal Title

      J. Electrochem. Soc

      Volume: 159 Pages: J34-J37

    • DOI

      10.1149/2.064202jes

    • Peer Reviewed
  • [Journal Article] Photoluminescence and Raman scattering spectra in (NH_4)_2XF_6 : Mn^<4+> (X=Si, Ge, Sn, and Ti) red phosphors2012

    • Author(s)
      Y. K. Xu and S. Adachi
    • Journal Title

      J. Electrochem. Soc

      Volume: 159 Pages: E11-E17

    • DOI

      10.1149/2.026201jes

    • Peer Reviewed
  • [Journal Article] Control of random lasing in ZnO/Al_2O_3 nanopowders2011

    • Author(s)
      T. Nakamura, B. P. Tiwari, and S. Adachi
    • Journal Title

      Appl. Phys. Lett

      Volume: 99 Pages: 231105-1-3

    • DOI

      10.1063/1.3665913

    • Peer Reviewed
  • [Journal Article] Optical properties of KCl : Sn^<2+> phosphors synthesized from aqueous KCl/SnCl_2 solutions2011

    • Author(s)
      J. Nara and S. Adachi
    • Journal Title

      J. Appl. Phys

      Volume: 110 Pages: 113508-1-8

    • DOI

      10.1063/1.3664916

    • Peer Reviewed
  • [Journal Article] Mn-activated Na_2SiF_6 red and yellowish-green phosphors : A comparative study2011

    • Author(s)
      T. Arai and S. Adachi
    • Journal Title

      J. Appl. Phys

      Volume: 110 Pages: 063514-1-9

    • DOI

      10.1063/1.3639298

    • Peer Reviewed
  • [Journal Article] Excited states of 3d^<3> electrons in K_2SiF_6 : Mn^<4+> red phosphor studied by photoluminescence excitation spectroscopy2011

    • Author(s)
      T. Arai and S. Adachi
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: 50 Pages: 092401-1-5

    • DOI

      10.1143/JJAP.50.092401

    • Peer Reviewed
  • [Journal Article] Direct synthesis and enhaced catalytic activities of platinum and porous-silicon composites by metal-assisted chemical etching2011

    • Author(s)
      T. Nakamura, B. P. Tiwari, and S. Adachi
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: 50 Pages: 081301-1-4

    • DOI

      10.1143/JJAP.50.081301

    • Peer Reviewed
  • [Journal Article] Optical properties of Mn^<4+>-activated Na_2SnF_6 and Cs_2SnF_6 red phosphors2011

    • Author(s)
      Y. Arai and S. Adachi
    • Journal Title

      J. Lumin

      Volume: 131 Pages: 2652-2660

    • DOI

      10.1016/j.jlumin.2011.06.042

    • Peer Reviewed
  • [Journal Article] Temperature-dependent photoluminescence properties of MnF_2 : Configurational-coordinate model analysis2011

    • Author(s)
      T. Arai and S. Adachi
    • Journal Title

      J. Appl. Phys

      Volume: 109 Pages: 103506-1-6

    • DOI

      10.1063/1.3592156

    • Peer Reviewed
  • [Journal Article] Synthesis of Si nanowire arrays in AgO/HF solution and their optical and wettability properties2011

    • Author(s)
      Y. Kato and S. Adachi
    • Journal Title

      J. Electrochem. Soc

      Volume: 158 Pages: K157-K163

    • DOI

      10.1149/1.3583598

    • Peer Reviewed
  • [Journal Article] Optical properties of SnCl_2 phosphor2011

    • Author(s)
      J. Nara and S. Adachi
    • Journal Title

      J. Appl. Phys

      Volume: 109 Pages: 083539-1-7

    • DOI

      10.1063/1.3576118

    • Peer Reviewed
  • [Journal Article] Surface-plasmon-enhanced band-edge emission from Au/GaN powders2011

    • Author(s)
      T. Nakamura, T. Hosaka, and S. Adachi
    • Journal Title

      Appl. Phys. Lett

      Volume: 98 Pages: 161906-1-3

    • DOI

      10.1063/1.3581214

    • Peer Reviewed
  • [Journal Article] Optical transitions and internal vibronic frequencies of MnF_6 ions in Cs_2SiF_6 and Cs_2GeF_6 red phosphors2011

    • Author(s)
      Y. Arai and S. Adachi
    • Journal Title

      J. Electrochem. Soc

      Volume: 158 Pages: J179-J183

    • DOI

      10.1149/1.3576124

    • Peer Reviewed
  • [Presentation] ZnSiF_6・6H_2O : Mn^<4+>赤色蛍光体の紫外光照射による劣化現象2014

    • Author(s)
      星野良介, 安達定雄
    • Organizer
      第61回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川県相模原市(青山学院大学)
    • Year and Date
      2014-03-19
  • [Book] The Handbook of Optical Constants of Metals: In Tables and Figures2012

    • Author(s)
      S. Adachi
    • Total Pages
      683
    • Publisher
      World Scientific
  • [Book] The Handbook of Optical Constants of Semiconductors: In Tables and Figures2012

    • Author(s)
      S. Adachi
    • Total Pages
      631
    • Publisher
      World Scientific
  • [Book] Properties and Applications2011

    • Author(s)
      S. Adachi, John Wiley & Sons, Inc
    • Total Pages
      51-73
    • Publisher
      Mercury Cadmium Telluride: Growth
  • [Patent(Industrial Property Rights)] 多孔性シリコン基板及びこれを利用する発光素子並びにそれらの製造方法2012

    • Inventor(s)
      安達定雄, 宮崎卓幸
    • Industrial Property Rights Holder
      群馬大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      特許第4960737号
    • Filing Date
      2012-03-30

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Published: 2015-06-25  

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