2013 Fiscal Year Final Research Report
Studies on synthesis of titanosilicate catalyst for the higly selective production of hydroquinone by phenol oxidation
| Project/Area Number |
23760741
|
|---|
| Research Category |
Grant-in-Aid for Young Scientists (B)
|
| Allocation Type | Multi-year Fund |
|---|
| Research Field |
Catalyst/Resource chemical process
|
|---|
| Research Institution | Yokohama National University |
|---|
Principal Investigator |
INAGAKI Satoshi 横浜国立大学, 大学院工学研究院, 准教授 (90367037)
|
|---|
| Project Period (FY) |
2011 – 2013
|
| Keywords | チタノシリケート / 選択酸化 / 形状選択性 / 疎水性 |
|---|
| Research Abstract |
The aim of this research is development of preparation methodology in Ti-containing MCM-68 with an MSE topology as a oxidation catlayst with highly selective production of hydroquinone in the phenol oxidation with hydrogen peroxide.
It is confirmed that shape-selectivity in 12-membered ring micropores of Ti-MCM-68 leads to highly selective production of hydroquinone, and the catalytic yield in Ti-MCM-68 can be improved by the enhancement of its hydrophobicity.
|
