Synthesis and Properties of Novel Porphyrin Derivatives Containing Heteroatoms

2015 Fiscal Year Final Research Report

• Project/Area Number: 24350023
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Partial Multi-year Fund
• Section: 一般
• Research Field: Organic chemistry
• Research Institution: Nagoya University
• Principal Investigator: Shinokubo Hiroshi 名古屋大学, 工学(系)研究科(研究院), 教授 (50281100)
• Project Period (FY): 2012-04-01 – 2016-03-31
• Keywords: ポルフィリン / コロール / ヘテロ原子 / 金属錯体 / 近赤外色素 / π共役 / 芳香族 / 反芳香族

Outline of Final Research Achievements

Porphyrin is a representative functional molecule. In this research project, we focused on the synthesis of novel heteroatom-containing porphyrin analogues through coupling of dipyrrin metal complexes. The metal-templated strategy using dipyrrin metal complexes was found to be quite efficient to construct porphyrin-like cyclic π-conjugated systems consisting of the dipyrrin units and heteroatoms, which exhibit intriguing optical and electronic properties.

Free Research Field

有機構造化学