Synthesis and Reactivity of Diruthenium Complexes Containing a Bridging Tin Ligand

2014 Fiscal Year Final Research Report

• Project/Area Number: 24550083
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Multi-year Fund
• Section: 一般
• Research Field: Inorganic chemistry
• Research Institution: Osaka Prefecture University
• Principal Investigator: TAKEMOTO Shin 大阪府立大学, 理学(系)研究科(研究院), 准教授 (20347511)
• Project Period (FY): 2012-04-01 – 2015-03-31
• Keywords: スタンニレン錯体 / スタンニリン錯体 / ルテニウム錯体 / スズ配位子 / 異種金属錯体 / Ru-Sn触媒

Outline of Final Research Achievements

Bimetallic complexes containing ruthenium and tin are of great scientific interest because of their potential application as new homogeneous catalysts and as molecular models of industrially important heterogeneous Ru-Sn catalysts. In this research, a novel method for the introduction of a stannylene unit (SnX2) into a coordinatively unsaturated diruthenium has been developed and used to synthesize a series of diruthenium complexes containing a bimetallic Ru2Sn core structure. Catalytic activity as well as some interesting stoichiometric reactivity of the resulting Ru2Sn complexes have been revealed.

Free Research Field

有機金属化学