Syntheses of noble signal transduction molecules possessing two orthogonally oriented redox moieties and their application to logical gates
| Project/Area Number |
19550138
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (C)
|
| Allocation Type | Single-year Grants |
|---|
| Section | 一般 |
|---|
| Research Field |
Functional materials chemistry
|
|---|
| Research Institution | Shizuoka University |
|---|
Principal Investigator |
UEDA Kazumasa Shizuoka University, 工学部, 教授 (10275290)
|
|---|
| Co-Investigator(Kenkyū-buntansha) |
KOKADO Satoshi 静岡大学, 工学部, 准教授 (50377719)
|
|---|
| Project Period (FY) |
2007 – 2010
|
| Project Status |
Completed (Fiscal Year 2010)
|
| Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2010: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2009: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2008: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2007: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
|
|---|
| Keywords | 直交配向分子 / 情報伝達素子 / 論理回路 / レドックス中心 / ヨウ素置換 / テトラチアフルバレノチオキノン-1,3-ジチオールメチド / Halogen bonding / ヨウ素の置換 / 分子素子 / クーロン相互作用 / テトラチアフルバレン / 非対称型 / 酸化還元挙動 / 二電子一段階 |
|---|
| Research Abstract |
Constructing of noble signal transduction molecules without the use of electrical conduction is one of the current issues for power saving function in logical gates. Our approach to overcome this issue is employing charge propagation for signal transduction system. One of the candidates for such system is a molecule possessing two orthogonally oriented redox moieties. We have succeeded in the syntheses of the iodine group substituted tetrathiafulvalenothioquinone-1,3-dithiolemthide derivatives and arranging them orthogonally by halogen bonding in the solid state.
|
Report
(6 results)
Research Products
(70 results)
-
[Journal Article] Syntheses, crystal structures and DFT calculations of 2-[4, 5-bis(ethylsulfanyl)-1, 3-dithiol-2-ylidene]-5-(4, 5-diiodo-1, 3-dithiol-2-ylidene)-1, 3-dithiolan-4-thione and-one2010
Author(s)
K.Ueda, K.Suzuki, K.Suzuki, K.Yoza, T.Ishida
-
Journal Title
Physica B : Physics of Condensed Matter. 405(11)
Related Report
Peer Reviewed
-
-
-
[Journal Article] Syntheses, crystal structures and DFT calculations of 2-[4,5-bis(ethylsulfanyl)- 1, 3-dithiol-2-ylidene]-5-(4,5-diiodo-1,3-dithiol-2-ylidene)-1, 3-dithiolan-4-thione and -one2010
Author(s)
K.Ueda, K.Suzuki, K.Suzuki, K.Yoza, T.Ishida
-
Journal Title
Physica B : Physics of Condensed Matter.
Volume: 405
Related Report
Peer Reviewed
-
-
-
[Journal Article] (Syntheses, crystal structures and DFT calculations of 2-[4,5-bis(ethylsulfanyl)-1,3-dithiol-2-ylidene]-5-(4,5-diiodo-1,3-dithiol-2-ylidene)-1, 3-dithiolan-4-thione and -one2010
Author(s)
K.Ueda, K.Suzuki, K.Suzuki, K.Yoza, T.Ishida
-
Journal Title
Physica B : Physics of Condensed Matter (in press)
Related Report
Peer Reviewed
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
[Journal Article] Syntheses, crystal structures and DFT calculations of 2-[4,5-bis(ethyl- sulfanyl)-1,3-dithiol-2-ylidene]-5-(4,5-diiodo-1,3-dithiol-2-ylidene)-1,3-dithiolan-4-thione and one
Author(s)
K. Ueda, K. Suzuki, K. Suzuki, K. Yoza, T. Ishida
-
Journal Title
Physica B : Physics of Condensed Matter
Related Report
Peer Reviewed
-
-
-
-
-
-
-
[Presentation] Syntheses, and crystal structures of 5-[4-(4,5-diiodo-1,3-dithiol-2-ylidene)-5-thioxo-1,3-dithiolan-2-ylidene][1,3]dithiolo[4,5-d][1, 3]dithiol-2-one and 5-[4-(4,5-diiodo-1,3-dithiol-2-ylidene)-5-oxo-1,3-dithiolan-2-ylidene][1,3]dithiolo[4,5-d][1,3]dithiol-2-one2010
Author(s)
K.Ueda, K.Suzuki
Organizer
2010 International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2010)
Place of Presentation
Kamehameha Halls II and III (Convention Center), Hawaii, USA
Year and Date
2010-12-17
Related Report
-
-
-
-
[Presentation] Syntheses, and crystal structures of 5-[4-(4, 5-diiodo-1, 3-dithiol-2-ylidene)-5-thioxo-1, 3-dithiolan-2-ylidene][1, 3]dithiolo[4, 5-d][1, 3]dithiol-2-one and 5-[4-(4, 5-diiodo-1, 3-dithiol-2-ylidene)-5-oxo-1, 3-dithiolan-2-ylidene][1, 3]dithiolo[4, 5-d][1,3]dithiol-2-one2010
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
