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Development of Fullerene Monolayer Characterized by Fluoroalkyl and Gemini

Research Project

Project/Area Number 23550216
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Organic industrial materials
Research InstitutionKyoto Institute of Technology

Principal Investigator

KAWASE TOKUZO  京都工芸繊維大学, 工芸科学研究科, 教授 (60152956)

Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2013: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2012: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2011: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Keywordsフラーレン / Aziridinofullerene / 単分子膜 / 表面圧-面積測定 / 2鎖多親水基型 / フルオロメチレン鎖 / フルオロアルキル基3鎖型 / フルオロアルキル基 / 表面圧‐面積曲線 / フルオロアルキル鎖 / Gemini / アジリジノフラーレン
Research Abstract

In this study, with focusing on the alignment control of C60 monolayer, aziridinofullerene deicatives were synthesized to investigate the new concepts of (1) two-chain and multi-hydrophilic structure and (2) the rigid fluoroalkyl chain, and also (3) a novel film forming method of C60 over the monolayer of three-fluoroalkyl chain material as matrix molecules.
From surface pressure-area measurements, C2v symmetry aziridinofullerenes showed the limiting area of 1.25nm2. Also, the rigidity of fluoroalkyl chain was proved very effective in the alignment control of C60. In addition, C60 monolayer formation would proceed successfully over the monolayer of matrix molecules.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (4 results)

All 2013 2011 Other

All Journal Article (3 results) (of which Peer Reviewed: 2 results) Remarks (1 results)

  • [Journal Article] 両親媒性アジリジノフラーレン誘導体の合成とその膜形成挙動2013

    • Author(s)
      川瀬徳三・石田夕香・今津亜理沙・老田達生・南方聖司・寉岡亮治
    • Journal Title

      材料技術

      Volume: Vol. 31、No. 1 Pages: 1-11

    • NAID

      40020099963

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] 両親媒性アジリジノフラーレン誘導体の合成とその膜形成挙動2013

    • Author(s)
      川瀬徳三、石田夕香、今津亜理沙、老田達生、南方聖司、寉岡亮治
    • Journal Title

      材料技術

      Volume: Vol. 31、 No.1 Pages: 1-11

    • NAID

      40020099963

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] フラーレン単分子膜2011

    • Author(s)
      川瀬 徳三
    • Journal Title

      表面

      Volume: Vol. 49 Pages: 185-211

    • NAID

      40019075386

    • Related Report
      2011 Research-status Report
  • [Remarks] 雑誌論文①により、平成25年度材料技術研究協会論文賞を受賞した。 (総説)川瀬徳三、フラーレン単分子膜、表面、Vol. 49、No. 6、185-211 (2011)

    • Related Report
      2013 Final Research Report

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Published: 2011-08-05   Modified: 2019-07-29  

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