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Investigation of new ionic plastic crystals in a new class of plastic crystal

Research Project

Project/Area Number 23550230
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic industrial materials
Research InstitutionYokohama City University

Principal Investigator

HONDA Hisashi  横浜市立大学, 生命ナノシステム科学研究科, 准教授 (30295505)

Project Period (FY) 2011-04-28 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2014: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2013: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2012: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2011: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords柔粘性結晶 / 柔粘性イオン結晶 / イオン伝導体 / Rotaor結晶 / 固体NMR
Outline of Final Research Achievements

Plastic crystals are soft solid materials. Depending on their constituent particles, they can be classified as ionic or molecular plastic crystals. In both types, the constituents are isotropically rotated at each crystal-lattice point in either a NaCl- or CsCl-type cubic system. The particle has fused orientation, and the gravity point of each particle is ordered. This situation is the opposite of that seen in liquid crystals. In this study, 16 crystals were constructed in a new region of ionic plastic crystal, where the cations and anions are held together by weak interactions. In addition, these crystals showed high conductivities of ca. 10-3 S cm-1 at around room temperatures.

Report

(5 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (14 results)

All 2015 2014 2013 2012 2011 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results,  Acknowledgement Compliant: 4 results) Presentation (8 results) (of which Invited: 1 results)

  • [Journal Article] Electrical Conductivity, Differential Scanning Calorimetry, X-ray Diffraction, and 7Li Nuclear Magnetic Resonance Studies of n-CxH(2x+1)OSO3Li (x = 12, 14, 16, 18, and 20)2015

    • Author(s)
      Satoru Hirakawa, Yoshiaki Morimoto, and Hisashi Honda
    • Journal Title

      Hyperfine Interactions

      Volume: 230 Issue: 1-3 Pages: 101-113

    • DOI

      10.1007/s10751-014-1087-7

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 1H and 13C NMR and Electrical Conductivity Studies on New Ionic Plastic Crystals of Tetraalkylammonium Tetraethylborate2015

    • Author(s)
      Satoru Hirakawa and Hisashi Honda
    • Journal Title

      Z. Naturforsch

      Volume: 70

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Investigation of New Ionic Plastic Crystals in NR4BBu4 (R = Me, Et, Pr, Bu, Pen)2014

    • Author(s)
      Tomoyuki Hayasaki, Satoru Hirakawa, and Hisashi Honda
    • Journal Title

      Am. Chem. Sci. J.

      Volume: 4 Issue: 6 Pages: 745-758

    • DOI

      10.9734/acsj/2014/10339

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Investigation of New Ionic Plastic Crystals in Tetraalkylammonium Tetrabuthylborate2014

    • Author(s)
      Tomoyuki Hayasaki, Satoru Hirakawa, and Hisashi Honda
    • Journal Title

      Z. Naturforsch.

      Volume: 69a Issue: 8-9 Pages: 433-440

    • DOI

      10.5560/zna.2014-0029

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] New Ionic Plastic Crystals of NR4BEt3Me ( R = Me, Rt) and NRxR’4-xBEt3Me (R = Et, R’ = Me, Pr, x = 1-3) in a New Class of Plastic Crystals2013

    • Author(s)
      Tomoyuki Hayasaki, Satoru Hirakawa, and Hisashi Honda
    • Journal Title

      Bull. Chem. Soc. Jpn.

      Volume: 86 Issue: 8 Pages: 993-1001

    • DOI

      10.1246/bcsj.20130040

    • NAID

      10031189245

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Electrical Conductivity, DSC, XRD, and 7Li NMR Studies of Rotator Crystals n-C21H43COOLixK(1-x) (0.33 ≤ x ≤ 0.50), n-CmH(2m+1)COOLi, and n-CmH(2m+1)COOK (m = 13, 15, 17, 19, and 21)2013

    • Author(s)
      Tomoyuki Hayasaki, Hisashi Honda, and Satoru Hirakawa
    • Journal Title

      Hyperfine Interactions

      Volume: 222 Issue: 1-3 Pages: 27-42

    • DOI

      10.1007/s10751-012-0670-z

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] New Ionic Plastic Crystals formed by Cage Type Cations of 1-methyl-4-aza-1-azoniabicyclo[2,2,2]octane and 1-ethyl-4-aza-1-azoniabicyclo[2,2,2]octane with Anions of BEt3Me and BEt42015

    • Author(s)
      Satoru, Hirakawa, Yuka Kotani, and Hisashi Honda
    • Organizer
      PACIFICHEM 2015
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2015-12-15 – 2015-12-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] 球状イオンを用いた新規柔粘性イオン結晶の開発2014

    • Author(s)
      平川悟・早崎智之・本多尚
    • Organizer
      分子科学討論会
    • Place of Presentation
      広島大学
    • Year and Date
      2014-09-21 – 2014-09-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] 二価イオンを用いた新規柔粘性イオン結晶の開発2013

    • Author(s)
      平川悟・本多尚
    • Organizer
      分子科学討論会
    • Place of Presentation
      京都テルサ
    • Related Report
      2013 Research-status Report
  • [Presentation] Electrical Conductivity, DSC, XRD, and 7Li NMR Studies of Rotator Crystals n-C21H43COOLixK(1-x) (0.33 ≤ x ≤ 0.50), n-CmH(2m+1)COOLi, and n-CmH(2m+1)COOK (m = 13, 15, 17, 19, and 21)2012

    • Author(s)
      Tomoyuki Hayasaki, Hisashi Honda, and Satoru Hirakawa
    • Organizer
      4th Joint International Conference on Hyperfine Interactions and International Symposium on Nuclear Quadrupole Interactions
    • Place of Presentation
      北京(中国)
    • Related Report
      2012 Research-status Report
  • [Presentation] 固体NMRにおけるBEt3Me塩を用いた柔粘性結晶の物性研究2012

    • Author(s)
      平川悟・早崎智之・本多尚
    • Organizer
      第51回NMR討論会
    • Place of Presentation
      ウィンクあいち(愛知県)
    • Related Report
      2012 Research-status Report
  • [Presentation] 新規有機イオン柔粘性結晶(NR4BR'4)の物性2012

    • Author(s)
      早崎智之・本多尚
    • Organizer
      日本化学会春年会
    • Place of Presentation
      慶應義塾大学日吉キャンパス
    • Related Report
      2011 Research-status Report
  • [Presentation] 新規柔粘性イオン結晶の物性2011

    • Author(s)
      早崎智之・本多尚
    • Organizer
      分子科学討論会
    • Place of Presentation
      札幌コンベンションセンター
    • Related Report
      2011 Research-status Report
  • [Presentation] 新しい柔粘性イオン結晶の開発

    • Author(s)
      早崎智之・本多尚
    • Organizer
      第51回固体NMR・材料フォーラム
    • Place of Presentation
      産業技術総合研究所(東京都)
    • Related Report
      2012 Research-status Report
    • Invited

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Published: 2011-08-05   Modified: 2019-07-29  

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