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Investigation of organic semiconductor/inorganic semiconductor heterojunctions and organic semiconductor heterojunctions

Research Project

Project/Area Number 26420283
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionOsaka Electro-Communication University

Principal Investigator

MATSUURA Hideharu  大阪電気通信大学, 工学部, 教授 (60278588)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywords有機薄膜太陽電池 / 有機/無機半導体ヘテロ接合 / バルクへテロ接合 / 接合特性 / 有機半導体 / 有機半導体/無機半導体ヘテロ接合 / 有機半導体/有機半導体ヘテロ接合 / 薄膜 / 有機半導体/無機半導体へテロ接合 / 欠陥評価 / 有機半導体/有機半導体へテロ接合
Outline of Final Research Achievements

We investigated the relationship between junction properties and solar-cell properties in inverse-type bulk-heterojunction (P3HT/PCBM) organic solar cells. It is found that the open-circuit voltage (VOC) increased with light-exposed time. In order to understand this increment of VOC, the built-in potential (VB) in the bulk-heterojunction was estimated from the frequency dependence of its impedance. It is found that VOC is proportional to VB.
Next, we fabricated P3HT/n-type crystalline silicon (n c-Si) heterojunctions, which are expected to be a high-efficiency simple-structure solar cell. We investigated the junction properties. In the current-voltage characteristics, the P3HT/n c-Si heterojunctions exhibited a rectifying property. At high frequency (200 kHz), the capacitance of the heterojunction using high-resistive n c-Si depended on applied voltage, while that using low-resistive n c-Si did not depend. We have been making a model to explain this experimental result.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (1 results)

All 2015

All Presentation (1 results)

  • [Presentation] 逆型有機薄膜太陽電池の経年劣化に関して2015

    • Author(s)
      鍔優、松浦秀治
    • Organizer
      電気関係学会関西連合大開
    • Place of Presentation
      摂南大学(大阪府・寝屋川市)
    • Year and Date
      2015-11-14
    • Related Report
      2015 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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