2016 Fiscal Year Final Research Report
Development of transition metal catalytic system converting halosilane into hydrosilane
| Project/Area Number |
15K13662
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic chemistry
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| Research Institution | Osaka City University |
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Principal Investigator |
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| Project Period (FY) |
2015-04-01 – 2017-03-31
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| Keywords | クロロシラン / ヒドロシラン / 還元反応 |
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| Outline of Final Research Achievements |
Si-H is an important bond because it is readily converted into various Si-X bonds. An Si-H bond has been prepared by the reaction of an Si-Cl bond with LiAlH4. However, LiAlH4 is too strong to reduce an undesired portion. In this project, we found that NaBH4, a milder reducing reagent, can convert an Si-Cl bond into an Si-H bond without reducing another portion. The reaction was completed by 15 min stirring at room temperature in acetonitrile.
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| Free Research Field |
錯体化学
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