Selective Growth of CVD-based Carbon Nanotubes through the Nanostructured Control and Their Novel Multi-functions

2011 Fiscal Year Final Research Report

• Project/Area Number: 19002007
• Research Category: Grant-in-Aid for Specially Promoted Research
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering; Chemistry
• Research Institution: Shinshu University
• Principal Investigator: ENDO Morinobu 信州大学, 工学部, 教授 (10021015)
• Co-Investigator(Kenkyū-buntansha): HAYASHI Takuya 信州大学, 工学部, 准教授 (80313831) ; KIM Yoong arm 信州大学, 工学部, 准教授 (70362100) ; KIM Yong jung 信州大学, カーボン科学研究所, 准教授 (50402128) ; KOYAMA Shozo 信州大学, 医学部, 教授 (00115346) ; HANIU Hisao 信州大学, 医学部, 助教 (30252050) ; FUJII Chifumi 信州大学, 医学部, 助教 (10361982) ; SAITO Naoto 信州大学, 医学部, 教授 (80283258) ; USUI Yuki 信州大学, エキゾチック・ナノカーボンの創成と応用プロジェクト拠点, 准教授 (00467169)
• Project Period (FY): 2007 – 2011
• Keywords: カーボンナノチューブ / 構造解析・制御 / 触媒気相法 / 物性 / 材料科学的安全性評価

Research Abstract

Carbon nanotube(CNT) has been recognized as a key material that drives the green innovation to generate new technology in a wide range of applications such as novel semiconductor, advanced composites, environmental materials and possible bio-applications. Present project aims especially to exploit a way to precise control of the growth and structure of double-walled(DWNT), and multi-walled CNT(MWNT), to reveal their growth mechanism, and to selectively grow desired CNT. The goal is to contribute to basic science, applications and understanding the basic toxicity aspect of CNT, from viewpoint of materials science, through an exact control of such as the microscopic structure and the electronic function. From the viewpoint of safe-nanotechnology as" Safe Innovation", the structurally controlled CNT should be pursued for promising growth of CNT science and technology

Research Products

• [Journal Article] Evaluation of CN Ttoxicity in comparison to tattoo ink (2011)
  • Author(s): Hara K, Aoki K, Usui Y, Shimizu M, NaritaN, Ogihara N, Nakamura K, Ishigaki N, SanoK, Haniu H, Kato H, Nishimura N, Kim Y. A, Taruta S, Saito N
  • Journal Title: Materials Today Volume: 14 Pages: 434-440
  • Peer Reviewed
• [Journal Article] Chirality-Dependent Transport in Double-Walled Carbon Nanotube Assemblies, The Role of Inner Tubes (2011)
  • Author(s): K. Fujisawa, K. Komiyama, H. Muramatsu, D. Shimamoto, T. Tojo, Y. A. Kim, T. Hayashi, M. Endo, K. Oshida, M. Terrones, M. S. Dresselhaus
  • Journal Title: ASC NANO Volume: 5, 9 Pages: 7457-7577
  • DOI: DOI:10.1021/nn202541c
  • Peer Reviewed
• [Journal Article] Mass-Produced Multi-Walled Carbon Nanotubes as Catalyst Supports for Direct Methanol Fuel Cells (2011)
  • Author(s): I. Y. Jang, K. C. Park, Y. C. Jung, S. H. Lee S. M. Song, H. Muramatsu, Y. J. Kim, M. Endo
  • Journal Title: Journal of Nanoscience and Nanotechnology Volume: 11 Pages: 675-680
  • DOI: doi:10.1166/jnn.2011.3229
  • Peer Reviewed
• [Journal Article] Bulk Synthesis of Narrow Diameter and Highly Crystalline Triple-Walled Carbon Nanotubes by Coalescing Fullerene Peapods (2011)
  • Author(s): H. Muramatsu, D. Shimamoto, T. Hayashi, Y. A. Kim, M. Endo, M. Terrones, M. Dresselhaus
  • Journal Title: Advanced Materials Volume: 23 Pages: 1761-1764
  • DOI: DOI:10.1002/adma.201004709
  • Peer Reviewed
• [Journal Article] Toxicoproteomic evaluation of carbonnanomaterials in vitro (2011)
  • Author(s): Hisao Haniu, Yoshikazu Matsuda, YukiUsui, Kaoru Aoki, Masayuki Shimizu, Nobuhide Ogihara, Kazuo Hara, MasanoriOkamoto, Seiji Takanashi, Norio Ishigaki, Koichi Nakamura, Hiroyuki Kato, Naoto Saito
  • Journal Title: Journal of Proteomics Volume: 74 Pages: 2703-2712
  • DOI: doi:10.1016/j.jprot.2011.03.004
  • Peer Reviewed
• [Journal Article] Tunable Raman spectroscopy study of CVD and peapod-derived bundled and individual double-wall carbon nano-tubes (2010)
  • Author(s): F. Villapand-Peaz, L. G. Moura, C. Fantini, H. Muramatsu, T. Hayashi, Y. A. Kim, M. Endo, M. Terrones, M. A. Pimenta, M. S. Dresselhaus
  • Journal Title: PHYSICALREVIEW B Volume: 82 Pages: 155416-1-9
  • DOI: DOI:10.1103/PhysRevB.82.155416
  • Peer Reviewed
• [Journal Article] Optically Active Multi-Walled Carbon Nanotubes for Transparent, Conductive Memory-Shape Polyurethane Film (2010)
  • Author(s): Y. C. Jung, H. H. Kim, Y. A. Kim, J. H. Kim, J. W. Cho, M. Endo, M. S. Dresselhaus
  • Journal Title: Macromolecules Volume: 43 Pages: 6106-6112
  • DOI: DOI:10.1021/ma101039y
  • Peer Reviewed
• [Journal Article] Covalent Attachment of Aromatic Diisocyanate to the Sidewalls of Singleand Double-Walled Carbon Nanotubes (2010)
  • Author(s): Yong Chae Jung, Hiroyuki Muramatsu, Takuya Hayashi, Jin Hee Kim, Yoong Ahm Kim, Morinobu Endo, Mildred S. Dresselhaus
  • Journal Title: Eur. J. Inorg. Chem Volume: 27 Pages: 4305-4308
  • DOI: DOI:10.1002/ejic.201000507
  • Peer Reviewed
• [Journal Article] High-Capacitance supercapacitors using nitrogen-decorated porous carbon derived from novolac resin containing peptide linkage (2010)
  • Author(s): Y. J. Kim, I. Y. Jang, K. C. Park, Y. C. Jung, T. Oka, S. Iinou, Y. Komori, T. Kozutsumi, T. Hashiba, Y. A. Kim, M. Endo
  • Journal Title: Electrochimica Acta Volume: 55 Pages: 5624-5628
  • DOI: doi:10.1016/j.electacta.201004.094
  • Peer Reviewed
• [Journal Article] High Performance Rubber Sealant for Preventing Water Leaks (2010)
  • Author(s): Fujisawa, Y. A. Kim, T. Hayashi, H. Ueki, S. Iinou
  • Journal Title: Ind. Eng. Chem. Res Volume: 49 Pages: 9798-9802
  • DOI: Doi:10.1021/ie1008663
  • Peer Reviewed
• [Journal Article] Electroactive shape memory performance of polyurethane composite having homogeneously dispersed and covalently crosslinked carbon nanotubes (2010)
  • Author(s): Y. C. Jung, H. J. Yoo, Y. A. Kim, J. W. Cho, M. Endo
  • Journal Title: Carbon Volume: 48 Pages: 1598-1603
  • DOI: doi:10.1016/j.carbon.2009.12.0581016/j.carbon.2009.12.058
  • Peer Reviewed
• [Journal Article] A simple route to short cup-stacked carbon nanotubes by sonication (2010)
  • Author(s): Daisuke Shimamoto, Kazunori Fujisawa, Hiroyuki Muramatsu, Takuya Hayashi, YoongAhm Kim, Takahashi Yanagisawa, Morinobu Endo, Mildred S. Dresselhaus
  • Journal Title: Carbon Volume: 48 Pages: 3643-3647
  • DOI: doi:10.1016/j.carbon.2010.05.040
  • Peer Reviewed
• [Journal Article] Boron Atoms as Loop Accelerator and Surface Stabilizer in Platelet-Type Carbon Nanofibers (2010)
  • Author(s): K. Fujiisawa, T. Hasegawa, D. Shimamoto, H. Muramatsu, Y. C. Yong, T. Hayashi, Y. A. Kim, M. Endo
  • Journal Title: ChemPhysChem Volume: 11 Pages: 2345-2348
  • DOI: DOI:10.1002/cphc.201000298
  • Peer Reviewed
• [Journal Article] Optical Spectroscopic Studies of Thermally Coalesced Single-Walled Carbon Nanotubes (2010)
  • Author(s): D. Shimamoto, H. Muramatsu, Y. J. Kim, Y. A. Kim, T. Hayashi, M. Endo, M. Terrones, M. S. Dresselhaus
  • Journal Title: J. Nanosci. and Nanotech Volume: 10, 6 Pages: 3878-3883
  • DOI: Doi:10.1166/jnn.2010.1990:10.1166/jnn.2010.1990
  • Peer Reviewed
• [Journal Article] Sensitive G-Band Raman Features for the Electrical Conductivity of Multi-Walled Carbon Nanotubes (2010)
  • Author(s): Y. A. Kim, H. Kakegawa, K. Fujisawa, D. Shimamoto, H. Muramatsu, J. H. Kim, Y. C. Jung, T. Hayashi, M. Endo, M. Terrones, M. S. Dresselhaus
  • Journal Title: J. Nanosci. Nanotech Volume: 10 Pages: 3940-3944
  • DOI: doi:10.1166.jnn.2010.1992
  • Peer Reviewed
• [Journal Article] Raman and Fluorescence Spectroscopic Studies of a DNA-Dispersed Double-Walled Carbon Nanotube Solution (2010)
  • Author(s): J. H. Kim, M. Kataoka, D. Shimamoto, H. Muramatsu, Y. C. Jung, T. Hayashi, Y. A. Kim, M. Endo, J. S. Park, R. Saito, M. Terrones, M. S. Dresselhaus
  • Journal Title: ACS NANO Volume: 4(2) Pages: 1060-1066
  • DOI: doi:10.1021/nn901871g
  • Peer Reviewed
• [Journal Article] Wall-to-wall stress induced in(6, 5) semiconducting nanotubes by encapsulation in metallic outer tubes of different diameters : A resonance Raman study of individual C60-derived doublewall carbon nanotubes (2010)
  • Author(s): F. Villalpando-Paez, H. Muramatsu, Y. A. Kim, H. Farhat, M. Endo, M. Terrones, M. S. Dresselhaus
  • Journal Title: Nanoscale Volume: 2(3) Pages: 406-411
  • DOI: DOI:10.1039/b9nr00268e
  • Peer Reviewed
• [Journal Article] Mouse pulmonary dose-and time course-responses induced by exposure to multi-walled-carbonnanotubes (2010)
  • Author(s): D. W. Poter, A. F. Hobbs, R. R. Mercer, N. Wu, M. G. Wolfarth, K. Sriram, S. Leonard, L. Bthelli, D. Schwegler-Berrry, S. Friend, M. Andrew. B. T. Chen, S. Tsuruoka, M. Endo and V. Castranova
  • Journal Title: Toxicology Volume: 269 Pages: 136-147
  • DOI: Doi:10.1016/j.tox.2009.10.017
  • Peer Reviewed
• [Journal Article] Properties of One-Dimensional Molybdenum Nanowires in a Confined Environment (2009)
  • Author(s): Vincent Meuier, Hiroyuki Muramatsu, Takuya Hayashi, Yoong Ahm Kim, Daisuke Shimamoto, Humberto Terrones, Mildred S. Dresselhaus, Mauricio Terrones, Morinobu Endo, B. G. Sumpter
  • Journal Title: NANO LETTERS Volume: 9, 4 Pages: 1487-1492
  • DOI: doi:10.1021/nl803438x
  • Peer Reviewed
• [Journal Article] Combined catalyst system for preferential growth of few-walled carbon nanotubes (2009)
  • Author(s): Yunfang Liu, Winadda Wongwiriyapan, Ki Chul Park, Hiroyuki Muramatsu, Kenji Takeuchi, Yoong Ahm Kim, Morinobu Endo
  • Journal Title: Carbon Volume: 47 Pages: 2543-2546
  • DOI: doi:10.1016/j.carbon.2009.05.009
  • Peer Reviewed
• [Journal Article] Strong and stable photoluminescence from the semiconducting inner tubes within double walled carbon nanotubes (2009)
  • Author(s): D. Shimamoto, H. Muramatsu, T. Hayashi, Y. A. Kim, M. Endo, J. S. Park, R. Saito, M. Terrones, M. S. Dresselhaus
  • Journal Title: Appl. Phys. Lett Volume: 94 Pages: 083106. 1-083106. 3
  • DOI: DOI:10.1063/1.3085966
  • Peer Reviewed
• [Journal Article] In vivo immunological toxicity in mice of carbon nanotubes with impurities (2009)
  • Author(s): Shozo Koyama, Yoong Ahm Kim, Takuya Hayashi, Kenji Takeuchi, Chifumi Fujii, Naomi Kuroiwa, Haruhide Koyama, Tamotsu Tukahara, Morinobu Endo
  • Journal Title: Carbon Volume: 47 Pages: 1365-1372
  • DOI: doi:10.1016/j.carbon.2009.01.028
  • Peer Reviewed
• [Journal Article] An anticorrosive magnesium/carbon nanotube composite (2008)
  • Author(s): M. Endo, T. Hayashi, I. Itoh, Y. A. Kim, D. Shimamoto, H. Muramatsu, Y. Shimizu, S. Morimoto, M. Terrones, S. Iinou, S. Koide
  • Journal Title: Appl. Phys. Lett Volume: 92 Pages: 063105-1-3
  • DOI: DOI:10.1063/1.2842411
  • Peer Reviewed
• [Journal Article] CdSe quantum dot-decorated double walled carbon nanotubes : The effect of chemical moieties (2008)
  • Author(s): Y. A. Kim, H. Muramatsu, K. C. Park, D. Shimamoto, Y. C. Jung, J. H. Kim, T. Hayashi, Y. Saito, M. Endo, M. Terrones and M. S. Dresselhaus
  • Journal Title: Appl. Phys. Lett Volume: 93 Pages: 051901-1-3
  • DOI: DOI:10.1063/1.2966341
  • Peer Reviewed
• [Journal Article] Simple Synthesis of Multiwalled Carbon Nanotubes from Natural Resources (2008)
  • Author(s): M. Endo, K. Takeuchi, Y. A. Kim, K. C. Park, T. Ichiki, T. Hayashi, T. Fukuyo, S. Iinou, D. S. Su. M. Terrones, M. S. Dresselhaus
  • Journal Title: ChemSusChem Volume: 1(10) Pages: 820-822
  • DOI: DOI:10.1002/cssc.200800150
  • Peer Reviewed
• [Journal Article] Extreme-Performance Rubber Nanocomposites for Probing and Excavating Deep Oil ResourcesUsing Multi-Walled Carbon Nanotubes (2008)
  • Author(s): M. Endo, T. Noguchi, M. Ito, K. Takeuchi, T. Hayashi, Y. A. Kim, T. Wanibuchi, H. Jinnai, M. Terrones, M. S. Dresselhaus
  • Journal Title: Adv. Funct. Mater Volume: 18 Pages: 3403-3409
  • DOI: DOI:10.1002/adfm.20081136
  • Peer Reviewed
• [Journal Article] Robust Conducting and Transparent Polymer Composites Using Surface-Modified and Individualized Double-Walled Carbon Nanotubes (2008)
  • Author(s): Y. C. Jung, D. Shimamoto, H. Muramatsu, Y. A. Kim, T. Hayashi, M. Terrones, M. Endo
  • Journal Title: Adv. Mater Volume: 20 Pages: 4509-4512
  • DOI: DOI:10.1002/adma.200801659
  • Peer Reviewed
• [Journal Article] Selective Optical Property Modification of Double-Walled Carbon Nanotubes by Fluorination (2008)
  • Author(s): T. Hayashi, D. Shimamoto, Y. A. Kim, H. Muramatsu, F. Okino, H. Touhara, T. Shimada, Y. Miyauchi, S. Maruyama, M. Terrones, M. S. Dresselhaus, M. Endo
  • Journal Title: ACS Nano Volume: 2(3) Pages: 485-488
  • DOI: doi:1021/nn700391w
  • Peer Reviewed
• [Journal Article] Synthesis and Isolation of Molybdenum Atomic Wires (2008)
  • Author(s): H. Muramatsu, T. Hayashi, Y. A. Kim, D. Shimamoto, M. Endo, M. Terrones and M. S. Dresselhaus
  • Journal Title: Nano Letters Volume: 8(1) Pages: 237-240
  • DOI: doi:10.1021/n10725188
  • Peer Reviewed
• [Presentation] Smart Grid for Energy Storage Devices (2011)
  • Author(s): 遠藤守信
  • Organizer: 2nd International Conference on Greenand Sustainable Chemistry(ICGSC)
  • Place of Presentation: Singapore
  • Year and Date: 2011-11-14
• [Presentation] Keynote lecture : Optical andtransport properties of Double-Walledcarbon nanotubes (2011)
  • Author(s): 遠藤守信
  • Organizer: Carbon2011
  • Place of Presentation: Shanghai, China
  • Year and Date: 2011-07-25
• [Presentation] Keynote lecture : Coaxial Carbon Nanotubes : Double-Walled Carbon Nanotubes (2010)
  • Author(s): 遠藤守信
  • Organizer: Carbon2010
  • Place of Presentation: Clemson University, USA
  • Year and Date: 2010-07-12
• [Presentation] Double-Walled Carbon Nanotubes : Synthesis (2009)
  • Author(s): 遠藤守信
  • Organizer: Carbon2009
  • Place of Presentation: Biarritz, France
  • Year and Date: 2009-06-15
• [Book] Synthesis, Characterization, and Applications, Encyclopedia of Nanoscience and Nanotechnology (2011)
  • Author(s): M. Endo, Y. A. Kim, T. Hayashi, H. Muramatsu, R. Saito, M. Terrones, M. S. Dresselhaus, Hari Singh Nalwa
  • Total Pages: 113-158
  • Publisher: American Scientific Publisher
• [Book] Battery Applications of Carbons, Carbonsfor Electochemical Energy Storage and Conversion Systems (2009)
  • Author(s): M. Endo, Y. J. Kim, K. C. Park
  • Total Pages: 469-507
  • Publisher: CRC Press
• [Book] Potential Application of Carbon Nanotubes, in Carbon Nanotubes : Advanced Topics in the Synthesis, Structure, Properties and Applications (2008)
  • Author(s): M. Endo, M. S. Strano, P. M. Ajayan
  • Total Pages: 13-62
  • Publisher: Springer, Topics Appl. Physics