2011 Fiscal Year Final Research Report
Synthesis and Function of New Cluster Complexes with Platinum to Metal Dative Bond
| Project/Area Number |
21550072
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Waseda University |
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Principal Investigator |
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| Project Period (FY) |
2009 – 2011
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| Keywords | 金属錯体化学 |
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| Research Abstract |
In this study, novel cluster complexes containing platinum to metal dative bond were synthesized. With use of gold(I) ion as an acceptor, new Pt-> Au dimer complexes with platinum to gold dative bond were synthesized and firstly characterized by X-ray crystallography. With use of mercury as an acceptor, novel type of isomer involving type of metal-metal bond, Pt(III)-Hg(0)-Pt(III) and Pt(II)-> Hg(I)-Pt(III) were synthesized.
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