2011 Fiscal Year Final Research Report
Nucleophilic Addition to Unsaturated Bonds Catalyzed by Rare Earth Metal Complexes
| Project/Area Number |
21550109
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | Yokohama National University |
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Principal Investigator |
SUZUKI Toshiaki 横浜国立大学, 教育人間科学部, 准教授 (20332257)
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| Project Period (FY) |
2009 – 2011
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| Keywords | 希土類金属 / 一酸化炭素 / カルボニル化 / ホルムアミド / アミジン / アセチレン |
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| Research Abstract |
The trialkyl rare earth metal complexes catalyzed the carbonylation of amines to give the corresponding formamides selectively at room temperature under low carbon monoxide pressure. This reaction is the first example of the carbonylation of amines under low temperature and low pressure of carbon monoxide. These catalysts catalyzed the reactions of amine with nitrile and isocyanide and the cis-selective head-to-head dimerization of 1-alkynes.
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