2010 Fiscal Year Final Research Report
Development of selective oxidation catalysts with multi-core active center using a theoretical approach
| Project/Area Number |
21750089
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Synthetic chemistry
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| Research Institution | Tohoku University (2010)
University of Tsukuba (2009) |
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Principal Investigator |
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| Project Period (FY) |
2009 – 2010
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| Keywords | 合成化学 / 計算化学 / ポリオキソメタレート / バナジウム / 銀 |
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| Research Abstract |
Catalyses of polyoxometalate catalysts with di-vanadium core were investigated. The catalyst with phosphorous as a central atom showed high performance for both epoxidation of alkenes and hydroxylation of alkanes. Catalysts for selective oxidation of aqueous poly-ols were also investigated. The combination of silver and noble metal showed high performance.
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