Asymmetric Photoreactions through Charge-Transfer Band Excitations

2015 Fiscal Year Final Research Report

• Project/Area Number: 23350018
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Organic chemistry
• Research Institution: Osaka University
• Principal Investigator: Mori Tadashi 大阪大学, 工学(系)研究科(研究院), 准教授 (70311769)
• Co-Investigator(Kenkyū-buntansha): FUKUHARA Gaku 大阪大学, 大学院工学研究科, 助教 (30505996)
• Project Period (FY): 2011-04-01 – 2015-03-31
• Keywords: 励起波長効果 / エキシプレックス / 励起CT錯体 / CT相互作用 / 温度効果 / エントロピー・エンタルピー / 蛍光スペクトル / 可視光利用

Outline of Final Research Achievements

In this study on the asymmetric photoreactions of chiral charge-transfer complex, we explored the generality of wavelength effect and mechanistic investigations. We employed three different photoreactions (two intermolecular and one intramolecular systems) to reveal the different excited complexes are always formed in all systems studied. We have published some of the results in three J. Am. Chem. Soc. papers (Impact Factor = 11.4), delivered the invited lectures in international conferences such as GRC Photochemistry, as well as contributed as invited review article in Chem. Soc. Rev. (Impact Factor = 24.9).

Free Research Field

有機光化学