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Studies on crystal behavior in storm glass

Research Project

Project/Area Number 24540415
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Mathematical physics/Fundamental condensed matter physics
Research InstitutionMeiji University

Principal Investigator

NAGASHIMA Kazushige  明治大学, 理工学部, 教授 (70339571)

Research Collaborator MITSUYA Takuro  
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2014: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2013: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2012: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Keywords溶液成長 / カンファー / ストームグラス / 形態形成 / 温度変動 / 結晶成長
Outline of Final Research Achievements

In the present study, the appearance of camphor crystals under cyclic temperature change in storm glass was studied. The precipitated crystals in the test tube showed the multi-layered pattern. It was found that each layer was originated from the different origin of formation processes such as initial nucleation, subsequent dendritic growth, nucleation in the solution above the dendrites, and the repetition of dendrite growth and nucleation. The analysis of each layer thickness as a function of elapsed time showed that the time dependence of layer thickness was categorized as four modes :constant, decay, pulse, oscillation depending on the origin of layer formation. According to the number of sample components, the related modes mentioned are different from each other. Thus, the complicated polycrystalline behavior under temperature change was characterized focusing on the time dependent layer thickness.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (11 results)

All 2015 2014 2012 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Acknowledgement Compliant: 1 results) Presentation (8 results)

  • [Journal Article] Cyclic growth and dissolution of camphor crystals in quinary, ternary, and binary solutions: A study on crystal behavior in storm glass2014

    • Author(s)
      Takuro Mitsuya, Kyohei Takahashi, Kazushige Nagashima
    • Journal Title

      Journal of Crystal Growth

      Volume: 401 Pages: 233-237

    • DOI

      10.1016/j.jcrysgro.2013.11.047

    • Related Report
      2014 Annual Research Report 2013 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Growth Pattern Dependence of Tetrahydrofuran Hydrates in Glass Beads of Two Sizes on Growth Rate and Glass Bead Mixing Ratio2014

    • Author(s)
      Michihiro Muraoka and Kazushige Nagashima
    • Journal Title

      Crystal Growth and Design

      Volume: 14(8) Issue: 8 Pages: 3813-3824

    • DOI

      10.1021/cg500298u

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Pattern variety of tetrahydrofuran clathrate hydrates formed in porous media2012

    • Author(s)
      M. Muraoka, K. Nagashima
    • Journal Title

      J. Physical Chemistry C

      Volume: vol.116, No.44 Issue: 44 Pages: 23342-23350

    • DOI

      10.1021/jp306224w

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] 霜柱状に成長するTHFハイドレート結晶へのゲスト分子拡散の影響2015

    • Author(s)
      伏屋孟、米山将基、長島和茂
    • Organizer
      日本化学会第95春季年会2015
    • Place of Presentation
      船橋市(日本大学)
    • Year and Date
      2015-03-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] 二相境界面におけるテトラヒドロフランハイドレートの成長過程2015

    • Author(s)
      高橋宏明、後藤弘旭、長島和茂
    • Organizer
      日本化学会第95春季年会2015
    • Place of Presentation
      船橋市(日本大学)
    • Year and Date
      2015-03-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] Growth of tetrahydrofuran clathrate hydrates in guest/host concentration boundary2014

    • Author(s)
      K. Nagashima, H. Goto, H. Takahashi
    • Organizer
      The 7th International Conference on Materials Science and Condensed Matter Physics
    • Place of Presentation
      Chisinau, the capital of the Republic of Moldova
    • Year and Date
      2014-09-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] THFハイドレートのパターン形成及びそのサイズスケールのデジタル画像解析2012

    • Author(s)
      村岡道弘、長島和茂
    • Organizer
      日本地球惑星科学連合2012年大会
    • Place of Presentation
      幕張メッセ国際会議場(千葉)
    • Related Report
      2012 Research-status Report
  • [Presentation] 二種類の粒径のガラスビーズ中において一方向成長する THF ハイドレートのパターン形成 -海底メタンハイドレートのパターン形成の機構解明へ向けて-

    • Author(s)
      村岡道弘、長島和茂
    • Organizer
      日本エネルギー学会
    • Place of Presentation
      工学院大学
    • Related Report
      2013 Research-status Report
  • [Presentation] Effects of cyclic temperature change on camphor crystals in Storm glass solution, camphor-ethanol-water solution, and camphor-ethanol solution

    • Author(s)
      Takuro Mitsuya, Kyohei Takahashi, Kazushige Nagashima
    • Organizer
      17th International Conference on Crystal Growth and Epitaxy ICCGE-17
    • Place of Presentation
      ワルシャワ大学、ポーランド
    • Related Report
      2013 Research-status Report
  • [Presentation] 温度変動下における2成分、3成分、5成分溶液中でのカンファー結晶の成長と溶解の挙動

    • Author(s)
      三矢拓郎、高橋恭平、長島和茂
    • Organizer
      日本化学会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Research-status Report
  • [Presentation] THFハイドレートの界面付着カイネティクスの実験的研究

    • Author(s)
      青木雄太、村岡道弘、長島和茂
    • Organizer
      日本化学会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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